0620/22 May/June 2025 Worked Answers (IGCSE Chemistry 0620 Extended)
40 questions · 40 marks · 45 minutes
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Worked answers for 40 questions
- Step 1: Melting is the change from solid to liquid and it needs energy to be supplied. Step 2: The water molecules absorb energy from the warm surroundings, which lets them break free of their fixed positions in the solid. Step 3: So as the ice melts the molecules gain energy.Method:Recall that melting requires energy to be taken in and decide what happens to the particles.Examiner tips
- Melting and boiling absorb energy; freezing and condensing release it.
- Step 1: As the gas is cooled its temperature drops until it reaches the boiling point, where it condenses to a liquid and the temperature stays constant, giving the first plateau. Step 2: Cooling continues until the freezing point, where the liquid freezes to a solid and the temperature stays constant again, giving a second, lower plateau. Step 3: So the graph falls, has a condensing plateau, falls, has a lower freezing plateau, then falls, which is the correct cooling curve.Method:Track the cooling from gas through condensing and freezing, marking a plateau at each change of state.Examiner tips
- On a cooling curve, plateaux are changes of state, ordered from higher to lower temperature.
- Step 1: The proton number of zinc is 30, and in a neutral atom the number of electrons equals the number of protons, so there are 30 electrons. Step 2: The number of neutrons is the nucleon number minus the proton number, which is 65 − 30 = 35. Step 3: So the atom has 30 protons, 30 electrons and 35 neutrons.Method:Use the proton number for protons and electrons, then subtract it from the nucleon number for neutrons.Examiner tips
- Proton number gives protons and electrons; subtract it from the mass number for neutrons.
- Step 1: The configuration 2,8,8 contains 18 electrons in total. Step 2: An argon atom has 18 electrons, and a chloride ion is a chlorine atom (17 electrons) that has gained one electron to give 18, so both have 18 electrons. Step 3: The aluminium ion has 13 − 3 = 10 electrons and the sodium ion has 11 − 1 = 10 electrons, so only particles 1 and 4 have the configuration 2,8,8.Method:Count the electrons in 2,8,8, then work out the electrons in each particle including its charge.Examiner tips
- For an ion, adjust the atom electron count by its charge before counting shells.
- Step 1: The relative atomic mass is the weighted average: . Step 2: This is . Step 3: To three significant figures the relative atomic mass is 240.Method:Apply the weighted-average formula using the isotope masses and their percentage abundances.Examiner tips
- A weighted average sits nearer the mass of the more abundant isotope.
- Step 1: Silicon(IV) oxide is a giant covalent solid in which silicon and oxygen atoms are joined throughout by covalent bonds. Step 2: Each silicon atom is bonded to four oxygen atoms in a tetrahedral arrangement like diamond, so that statement is correct. Step 3: It has no delocalised electrons (so it does not conduct), it is not a simple molecule, and its arrangement is like diamond, not graphite.Method:Recall the diamond-like giant covalent structure of silicon(IV) oxide and test each statement.Examiner tips
- Silicon(IV) oxide = giant covalent, diamond-like, four bonds per silicon, no conduction.
- Step 1: In the first experiment the 65 g of zinc exactly reacts with 32 g of sulfur to give 97 g of zinc sulfide, so this uses up all of both reactants. Step 2: Adding more sulfur (40 g) does not help because all 65 g of zinc has already reacted, so the zinc is the limiting reactant. Step 3: With no zinc left, the extra sulfur cannot react, so the mass of zinc sulfide stays at 97 g.Method:Compare the two experiments to see which reactant is completely used up and limits the product.Examiner tips
- Adding more of one reactant makes no extra product once the other reactant is used up.
- Step 1: Iron(III) oxide is and aluminium oxide is , so these correct formulae must appear. Step 2: Balancing then needs 2 aluminium atoms on the left and 2 iron atoms on the right. Step 3: This gives , which balances all the atoms.Method:Write the correct formulae for each compound, then balance the atoms on both sides.Examiner tips
- Fix the correct formulae first, then add coefficients to balance each element.
- Step 1: Moles = concentration × volume in dm³ = 0.50 × (500 ÷ 1000) = 0.25 mol. Step 2: Mass = moles × relative formula mass = 0.25 × 40. Step 3: This gives a mass of 10 g of sodium hydroxide.Method:Calculate the moles from concentration and volume, then convert to a mass.Examiner tips
- Always change cm³ to dm³ (divide by 1000) before using concentration.
- Step 1: Molten zinc oxide contains only zinc ions and oxide ions, with no water present. Step 2: At the cathode the positive zinc ions gain electrons and form zinc metal, while at the anode the negative oxide ions lose electrons and form oxygen. Step 3: So oxygen is made at the anode and zinc at the cathode.Method:Identify the ions in the molten compound, then send the metal to the cathode and non-metal to the anode.Examiner tips
- Electrolysing a molten compound gives the metal at the cathode and the non-metal at the anode.
- Step 1: At the cathode positive ions gain electrons (reduction). Step 2: In dilute sodium chloride the hydrogen ions are discharged in preference to sodium ions, because hydrogen is less reactive than sodium. Step 3: So two hydrogen ions gain two electrons to form a hydrogen molecule: .Method:Choose the cathode reaction where positive ions gain electrons, preferring the less reactive ion.Examiner tips
- Cathode = reduction = gain of electrons; the less reactive ion is discharged.
- Step 1: A fuel cell uses the reaction of hydrogen and oxygen to produce a voltage, so it converts chemical energy in the fuel into electrical energy. Step 2: The overall reaction is , giving only water (no carbon dioxide). Step 3: Hydrogen is not a fossil fuel, so only the statement about chemical energy becoming electrical energy is correct.Method:Recall how a hydrogen-oxygen fuel cell works and its single product, then test each statement.Examiner tips
- Fuel cells make only water and convert chemical energy directly into electrical energy.
- Step 1: The products are higher in energy than the reactants, so energy has been taken in from the surroundings, which makes the reaction endothermic. Step 2: Because the reaction absorbs energy from the surroundings, the surroundings lose energy and their temperature falls. Step 3: So the reaction is endothermic and the temperature of the surroundings decreases.Method:Compare the energy levels of products and reactants to classify the reaction and its effect on the surroundings.Examiner tips
- Endothermic: products higher on the diagram, energy absorbed, surroundings cool.
- Step 1: Forming bonds releases energy, so making bonds gives a negative (exothermic) enthalpy change. Step 2: Each methane molecule has four C–H bonds, so the energy released per mole is 4 × 413 = 1652 kJ. Step 3: Because the bonds are being formed, the enthalpy change is −1652 kJ.Method:Count the bonds formed, multiply by the bond energy, and make the sign negative for bond making.Examiner tips
- Bond forming is exothermic (negative); count every bond made.
- Step 1: A catalyst provides an alternative pathway with a lower activation energy, so it lowers , it does not raise it. Step 2: A catalyst does not change the energies of the reactants or products, so the enthalpy change stays the same. Step 3: A catalyst does not lower the collision frequency or raise the particles’ kinetic energy, so the only correct statement is that is unchanged.Method:Recall what a catalyst does and does not change, then test each statement.Examiner tips
- A catalyst changes the rate by lowering Ea, but ΔH for the reaction is unaffected.
- Step 1: The Contact process uses vanadium(V) oxide as the catalyst, not iron (iron is used in the Haber process). Step 2: The key step is carried out at a temperature of about 450 °C and only a low pressure of about 2 atmospheres, because a higher pressure gives little extra yield and is expensive. Step 3: So the correct conditions are a vanadium(V) oxide catalyst, a low pressure and about 450 °C.Method:Recall the standard Contact process conditions and pick the matching row.Examiner tips
- Match the catalyst to the process: vanadium(V) oxide = Contact process, iron = Haber process.
- Step 1: A reducing agent is the species that is itself oxidised, that is, it loses electrons (its oxidation state increases). Step 2: In equation 2 the iron goes from 0 in Fe to +2 in , and in equation 3 the iron goes from +2 in to +3 in , so in both the iron is oxidised and acts as the reducing agent. Step 3: In equation 1 the iron in is reduced (it gains electrons, so it is the oxidising agent), and in equation 4 the iron stays +2 throughout (no redox), so only equations 2 and 3 show the iron as a reducing agent.Method:Assign oxidation states to the iron in each equation and find where it increases.Examiner tips
- Track the oxidation state of the iron: increasing means oxidised, so it is the reducing agent.
- Step 1: A gas that turns damp red litmus paper blue is alkaline, and the common alkaline gas is ammonia. Step 2: Ammonia is released when an ammonium salt is warmed with a base, such as a basic oxide. Step 3: So the two substances are a basic oxide and an ammonium salt; potassium salts and acidic oxides do not release ammonia.Method:Identify the alkaline gas as ammonia, then choose the base plus ammonium salt that releases it.Examiner tips
- Ammonia (turns red litmus blue) is produced when an ammonium salt meets a base.
- Step 1: A strong acid is fully dissociated, so its equation uses a single forward arrow, while a weak acid is only partly dissociated, so its equation uses a reversible arrow. Step 2: Hydrochloric acid is strong, so has a forward arrow, and ethanoic acid is weak, so has a reversible arrow. Step 3: So the correct row gives HCl a full arrow and ethanoic acid a reversible arrow.Method:Match each acid to its strength, then choose the forward or reversible arrow accordingly.Examiner tips
- Use → for a strong acid and ⇌ for a weak acid to show the extent of dissociation.
- Step 1: Acidic oxides are formed by non-metals, while metal oxides such as calcium oxide and sodium oxide are basic. Step 2: Carbon dioxide, nitrogen dioxide and sulfur dioxide are all non-metal oxides, so all three are acidic. Step 3: Any set containing CaO or includes a basic oxide, so only , and are all acidic.Method:Classify each oxide as metal (basic) or non-metal (acidic) and pick the all-non-metal set.Examiner tips
- Spot the metal oxides (basic) and remove any set that contains one.
- Step 1: Going down the noble gases both the density and the boiling point increase, so krypton’s values must lie between those of argon and xenon. Step 2: The density must be between 0.9 and 5.9 g/dm³, and the boiling point between −186 and −108 °C. Step 3: A density of 3.8 g/dm³ and a boiling point of −153 °C both fall in these ranges, so they are the correct predictions.Method:Use the increasing trend down the group to place krypton between argon and xenon.Examiner tips
- Interpolate: a value between two neighbours must lie between their two values.
- Step 1: Like other metals, sodium is malleable, meaning it can be bent or hammered into shape. Step 2: As a Group I metal sodium is also a good conductor of electricity, has a low melting point and a low density. Step 3: So of the options given, only being malleable is a correct physical property of sodium.Method:Recall the physical properties of Group I metals and find the correct one.Examiner tips
- Remember Group I metals are soft, low-density and low-melting, yet still malleable conductors.
- Step 1: Down Group VII the elements change from gases (fluorine, chlorine) to a liquid (bromine) to solids (iodine, astatine). Step 2: Tennessine lies below astatine, which is already a solid, so the trend predicts tennessine is also a solid. Step 3: So at room temperature and pressure tennessine is expected to be a solid.Method:Follow the trend in state down Group VII to predict the state of the lowest element.Examiner tips
- Continue the gas-liquid-solid trend down the group to predict the heaviest member.
- Step 1: Chlorine is more reactive than bromine because reactivity decreases down Group VII. Step 2: The more reactive chlorine takes the place of the less reactive bromine, forming chloride ions and releasing bromine: . Step 3: So chlorine (the element) displaces bromine (the element) from the sodium bromide.Method:Use the reactivity order of the halogens to decide which element displaces which.Examiner tips
- Write it as element displaces element: chlorine displaces bromine.
- Step 1: An alloy contains atoms of different sizes, which disrupt the regular layers of atoms in the metal. Step 2: The different-sized atoms in brass stop the layers from sliding over each other easily, so brass is harder than pure copper. Step 3: Brass is a mixture (not a compound) and still conducts, copper conducts because of its free electrons (not free atoms), and a pure metal is softer, so only the statement about brass being harder is correct.Method:Use the idea of mixed-size atoms blocking layers to compare the hardness of an alloy and pure metal.Examiner tips
- Alloying distorts the layers, making alloys harder than the pure metal.
- Step 1: The given equations show magnesium > zinc > copper > silver and that tin > copper, but the position of tin relative to zinc is still unknown. Step 2: If zinc reacts with ions, then zinc is more reactive than tin, which fixes tin between zinc and copper. Step 3: This completes the order magnesium > zinc > tin > copper > silver, so the useful new information is that zinc reacts with ions.Method:Work out the order from the given reactions, then choose the test that fixes the only missing comparison.Examiner tips
- Identify the one pair whose order is still missing, then find the experiment that compares them.
- Step 1: The zinc coating keeps out water and oxygen, so galvanising is a barrier method, making statement 1 correct. Step 2: Even if the zinc is scratched, the more reactive zinc still corrodes in preference to the iron, so the iron is protected and does not rust quickly, making statement 2 wrong and statement 3 (sacrificial protection) correct. Step 3: Zinc, being more reactive, loses (donates) electrons more readily rather than accepting them, so statement 4 is wrong, leaving 1 and 3.Method:Judge each statement using how a more reactive coating protects iron physically and sacrificially.Examiner tips
- Zinc protects iron in two ways: a physical barrier and sacrificial (it corrodes first).
- Step 1: In the blast furnace, carbon monoxide is the reducing agent that removes oxygen from the iron(III) oxide. Step 2: The carbon monoxide reduces the iron(III) oxide to iron, forming carbon dioxide: . Step 3: Calcium is not used to reduce the ore, so the equations involving calcium do not represent the extraction of iron.Method:Identify the reduction of iron(III) oxide by carbon monoxide as the extraction reaction.Examiner tips
- The key blast-furnace reaction is reduction of Fe2O3 by CO to give iron and CO2.
- Step 1: Anhydrous copper(II) sulfate is white and turns blue when water is added, which is the standard test for water. Step 2: Anhydrous cobalt(II) chloride is blue and turns pink when water is added, the other test for water. Step 3: So copper(II) sulfate goes white to blue and cobalt(II) chloride goes blue to pink.Method:Recall the two standard tests for water and the direction of each colour change.Examiner tips
- These two colour changes are the chemical tests for the presence of water.
- Step 1: A catalytic converter removes the harmful carbon monoxide and nitrogen monoxide from the exhaust. Step 2: It does this by reacting them together so that carbon monoxide is oxidised to carbon dioxide and nitrogen monoxide is reduced to nitrogen: . Step 3: The other equations make harmful gases or carbon monoxide rather than removing them.Method:Choose the equation that turns the harmful exhaust gases into harmless carbon dioxide and nitrogen.Examiner tips
- The converter pairs CO with NO to give harmless CO2 and N2.
- Step 1: Carbon dioxide is a greenhouse gas that absorbs thermal energy radiated from the Earth, so statement 1 is correct, and burning fossil fuels has raised its atmospheric level, so statement 3 is correct. Step 2: By absorbing this energy it reduces the thermal energy lost to space, so statement 2 is wrong. Step 3: Other gases such as methane also cause global warming, so statement 4 is wrong, leaving statements 1 and 3.Method:Use what greenhouse gases do to judge each statement about carbon dioxide.Examiner tips
- Greenhouse gases trap heat (reduce loss to space); CO2 is one of several, not the only one.
- Step 1: Butan-2-ol has a chain of four carbon atoms (but-) and an –OH group (-ol) on carbon number 2. Step 2: Writing a four-carbon chain with the –OH on the second carbon gives . Step 3: So this is the structural formula of butan-2-ol.Method:Build the four-carbon chain and place the –OH on carbon 2 to match the name.Examiner tips
- Count the carbons for the stem name and check which carbon carries the –OH group.
- Step 1: An ester forms when the –OH of the alcohol reacts with the –COOH of the carboxylic acid, losing water and making a C(=O)–O ester linkage. Step 2: Ethanoic acid provides and methanol provides , which join to give methyl ethanoate, . Step 3: So the correct displayed formula is the methyl ethanoate structure with the ester linkage in the right place.Method:Combine the acid and alcohol parts through an ester linkage to build the correct displayed formula.Examiner tips
- Methanol + ethanoic acid → methyl ethanoate, CH3COOCH3, plus water.
- Step 1: Kerosene is the aircraft fuel fraction, so it is correctly used as jet fuel. Step 2: Bitumen is used to surface roads (not as a lubricant), naphtha is mainly a feedstock for making chemicals (not home heating), and refinery gas is used as a fuel for cooking and heating (not making chemicals). Step 3: So only kerosene matched with jet fuel is correct.Method:Recall the standard use of each petroleum fraction and find the correct pairing.Examiner tips
- Learn each fraction with its main use; kerosene = jet fuel is a key one.
- Step 1: Ethane is a saturated alkane, so with chlorine and ultraviolet light it undergoes substitution, where a chlorine atom replaces one hydrogen atom. Step 2: One hydrogen of ethane is replaced by a chlorine, giving chloroethane, , and the displaced hydrogen joins a chlorine to form hydrogen chloride, HCl. Step 3: So the products are and HCl.Method:Apply the substitution rule for an alkane and chlorine to find the chloroalkane and HCl.Examiner tips
- Alkane + Cl2 (UV) → chloroalkane + HCl by substitution.
- Step 1: The catalytic addition of steam to ethene is a fast, continuous process that gives pure ethanol. Step 2: Compared with fermentation, two clear advantages are that it produces a purer product and is a faster reaction. Step 3: Using renewable raw materials is an advantage of fermentation (ethene comes from finite petroleum), and using more energy is a disadvantage, so the correct pair is a purer product and a faster reaction.Method:Compare the two ethanol methods and pick the two genuine advantages of hydrating ethene.Examiner tips
- Hydration of ethene: fast, continuous, pure product; fermentation: renewable but slow and impure.
- Step 1: The repeat unit contains amide linkages, –N(H)–C(=O)–, so it is a polyamide made from a diamine and a dicarboxylic acid. Step 2: The –N(H)–CH₂–CH₂–N(H)– part comes from a two-carbon diamine, , and the –C(=O)–CH₂–CH₂–C(=O)– part comes from a dicarboxylic acid, . Step 3: So the correct monomers are this diamine and dicarboxylic acid, matching the chain lengths in the repeat unit.Method:Recognise the amide linkage, then split the repeat unit into the matching diamine and diacid monomers.Examiner tips
- Polyamide = diamine + dicarboxylic acid; match the carbon chains to the repeat unit.
- Step 1: A volume given to one decimal place, such as 26.3 cm³, needs apparatus with a fine, accurate scale. Step 2: A burette has a precise graduated scale and a tap, so it can deliver any accurate variable volume like 26.3 cm³. Step 3: A measuring cylinder is far less precise, and beakers and conical flasks only hold liquids, so the burette is the correct choice.Method:Choose the apparatus whose fine graduations allow an exact variable volume to be measured.Examiner tips
- For an accurate, variable volume to 0.1 cm³, use a burette.
- Step 1: During filtration, the insoluble solid is trapped on the filter paper and is called the residue, so X is the residue. Step 2: The liquid that passes through the filter paper is called the filtrate, so Y is the filtrate. Step 3: The filtrate is the aqueous salt solution, not pure water, so X is the residue and Y is the filtrate.Method:Use the filtration terms: residue for the solid on the paper, filtrate for the liquid collected.Examiner tips
- In filtration, name the trapped solid the residue and the collected liquid the filtrate.
- Step 1: Dissolving an impurity in a substance lowers its melting point and raises its boiling point. Step 2: So the melting point falls below −114 °C, to −116 °C, and the boiling point rises above 78 °C, to 79 °C. Step 3: So the impure ethanol melts at −116 °C and boils at 79 °C.Method:Apply the effect of an impurity to shift the melting point down and the boiling point up.Examiner tips
- Impurity: melting point goes down, boiling point goes up, and the ranges broaden.
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