May/June 2025 Paper 31 Worked Answers (IGCSE Chemistry 0620 Core)
53 questions · 80 marks · 75 minutes
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Worked answers for 53 questions
- Step 1: Potassium is in Group I, so an atom has one outer electron. Step 2: Losing that single electron gives one extra positive charge, so potassium forms a 1+ ion. Step 3: Magnesium forms a 2+ ion, aluminium a 3+ ion and oxygen a 2- ion, so only potassium forms a 1+ ion.Method:Use each element group number to work out the charge of the ion it forms.Examiner tips
- Group I metals form 1+ ions by losing their single outer electron.
- Step 1: The blast furnace is used to extract iron from iron ore by reduction with carbon. Step 2: Iron is below carbon in the reactivity series, so it can be reduced by carbon in the furnace. Step 3: Aluminium, potassium and magnesium are more reactive than carbon and are extracted by electrolysis, so the blast-furnace metal is iron.Method:Match the extraction method to the metal: carbon reduction for iron.Examiner tips
- Metals below carbon (e.g. iron) are extracted by reduction with carbon in a blast furnace.
- Step 1: Reactivity increases down Group I, and potassium is below sodium in Group I. Step 2: Potassium is therefore more reactive than sodium and, like other Group I metals, is soft enough to cut with a knife. Step 3: Iron, magnesium and aluminium are all less reactive than sodium, so the answer is potassium.Method:Use the trend in Group I reactivity to find the metal more reactive than sodium.Examiner tips
- Group I metals are soft and get more reactive going down the group.
- Step 1: Clean dry air is about 78% nitrogen and 21% oxygen, with small amounts of other gases. Step 2: The gas making up roughly 78% is therefore nitrogen. Step 3: Oxygen is about 21%, while carbon dioxide and argon are present in small or trace amounts, so the answer is nitrogen.Method:Recall the composition of clean dry air and pick the gas at about 78%.Examiner tips
- Remember the 78% nitrogen / 21% oxygen split of clean dry air.
- Step 1: Ammonia is an alkaline gas, so it is the gas tested with damp red litmus paper. Step 2: Ammonia turns the damp red litmus paper blue, identifying it. Step 3: Carbon dioxide, oxygen and nitrogen have different tests, so the gas identified with damp red litmus is ammonia.Method:Match each gas to its standard test and pick the one using damp red litmus.Examiner tips
- Ammonia is the only common alkaline gas: it turns damp red litmus blue.
- Step 1: Going down Group VII the elements change from gases to liquids to solids. Step 2: Bromine is the halogen that is a red-brown liquid at room temperature and pressure. Step 3: Fluorine and oxygen are gases and iron is a solid, so the liquid element is bromine.Method:Recall the states of the elements and pick the one that is liquid.Examiner tips
- Down Group VII: fluorine and chlorine gases, bromine liquid, iodine solid.
- Step 1: Aluminium forms a thin protective oxide layer that stops further corrosion. Step 2: This resistance to corrosion makes aluminium suitable for food containers and drink cans. Step 3: Iron rusts easily, and potassium and magnesium are too reactive, so the answer is aluminium.Method:Pick the element whose corrosion resistance makes it useful for food containers.Examiner tips
- Aluminium resists corrosion thanks to its protective oxide layer.
- Step 1: Transition elements are the block of metals between Group II and Group III in the centre of the Periodic Table. Step 2: Iron sits in this central transition block, so iron is a transition element. Step 3: Magnesium (Group II), potassium (Group I) and aluminium (Group III) are not in the transition block, so iron is the transition element.Method:Locate each element on the Periodic Table and pick the one in the central transition block.Examiner tips
- Iron, copper and zinc are common transition elements in the central block.
- Step 1: The formula contains a calcium ion and a carbonate ion, . Step 2: A compound of calcium with the carbonate ion is named calcium carbonate. Step 3: Calcium oxide is CaO and calcium chloride is , so is calcium carbonate.Method:Identify the ions in the formula and name the compound from them.Examiner tips
- = carbonate, O alone = oxide, Cl = chloride.
- Step 1: The mass of compounds is proportional to the volume of sea water. Step 2: The mass in 1750 cm³ = 19.0 × (1750 ÷ 1000) = 19.0 × 1.75. Step 3: This gives 33.25 g of compounds in 1750 cm³.Method:Set up the proportion of mass to volume and solve for the new mass.Examiner tips
- Mass is proportional to volume: multiply by (new volume ÷ original volume).
- Step 1: Using the solubility rules, all common potassium compounds are soluble, and so are all hydroxides of Group I metals. Step 2: Potassium hydroxide is therefore soluble in water. Step 3: Lead(II) chloride and silver chloride are insoluble chlorides, and most carbonates (magnesium carbonate) are insoluble, so the soluble compound is potassium hydroxide.Method:Apply the solubility rules to each compound and pick the soluble one.Examiner tips
- All sodium, potassium and ammonium salts are soluble; most carbonates are not.
- Step 1: Halide ions are tested by acidifying with dilute nitric acid and then adding aqueous silver nitrate. Step 2: With chloride ions a white precipitate of silver chloride forms. Step 3: A yellow precipitate indicates iodide ions, the sodium hydroxide test is for ammonium ions and limewater tests for carbon dioxide, so the correct test gives a white precipitate with silver nitrate.Method:Recall the silver nitrate halide test and match the colour to chloride.Examiner tips
- Chloride → white, bromide → cream, iodide → yellow precipitate with silver nitrate.
- Step 1: A sodium atom has 11 electrons arranged 2,8,1. Step 2: Losing the single outer electron leaves 10 electrons arranged 2,8. Step 3: Losing one negative electron leaves the ion with a charge of 1+, so the ion is 2,8 with a 1+ charge.Method:Take the atom configuration, remove the outer electron, and assign the matching charge.Examiner tips
- A Group I atom loses one electron to form a 1+ ion with a full outer shell.
- Step 1: In a liquid the particles are still close together but they are arranged irregularly, with no fixed pattern. Step 2: They have enough energy to move around and slide over each other. Step 3: So the particles in a liquid are close together but irregular and slide over one another.Method:Recall the kinetic particle description of a liquid for both arrangement and motion.Examiner tips
- Liquid = close together + irregular + sliding/flowing over each other.
- Step 1: Ionic compounds have strong forces between oppositely charged ions, giving high melting and boiling points. Step 2: When molten or dissolved, the ions are free to move and carry charge, so the compound conducts electricity. Step 3: So two properties are a high melting point and conducting electricity when molten or in aqueous solution.Method:Recall the typical physical properties of ionic compounds and choose two correct ones.Examiner tips
- Ionic compounds: high melting point + conduct when molten/aqueous.
- Step 1: Aquatic animals such as fish respire using dissolved oxygen in the water. Step 2: The gas essential for aquatic life is therefore oxygen. Step 3: Nitrogen is unreactive, carbon dioxide is a product of respiration and hydrogen is not normally dissolved, so the answer is oxygen.Method:Identify the dissolved gas used by aquatic animals in respiration.Examiner tips
- Dissolved oxygen is essential for aquatic life.
- Step 1: The group number of a main-group element equals the number of electrons in its outer shell. Step 2: Sulfur is in Group VI because it has 6 electrons in its outer shell. Step 3: The number of shells gives the period, and neutrons and relative atomic mass do not set the group, so the reason is 6 outer electrons.Method:Link the group number to the number of outer-shell electrons.Examiner tips
- Outer-shell electrons = group number for main-group elements.
- Step 1: The lower number (16) is the proton number, so each isotope has 16 protons and, being neutral atoms, 16 electrons. Step 2: Neutrons = mass number − proton number, so has 33 − 16 = 17 neutrons and has 36 − 16 = 20 neutrons. Step 3: So is 16 protons, 17 neutrons, 16 electrons and is 16 protons, 20 neutrons, 16 electrons.Method:Read the proton number from the bottom figure and subtract it from the mass number for neutrons.Examiner tips
- Bottom number = protons (= electrons); top number = protons + neutrons.
- Step 1: Fossil fuels such as coal and oil contain sulfur compounds. Step 2: When these fuels are burned in power stations and engines, the sulfur is oxidised to sulfur dioxide, which enters the air. Step 3: Photosynthesis, evaporation and respiration do not produce sulfur dioxide, so the source is burning fossil fuels.Method:Recall how sulfur dioxide is produced and pick the matching source.Examiner tips
- Burning fossil fuels that contain sulfur is the main source of sulfur dioxide.
- Step 1: Sulfur dioxide dissolves in rain water and is oxidised to form sulfuric acid. Step 2: This makes the rain acidic, producing acid rain that damages plants, lakes and buildings. Step 3: Sulfur dioxide is not a major greenhouse gas and does not form ozone or help breathing, so its adverse effect is acid rain.Method:Recall the environmental problem linked to sulfur dioxide.Examiner tips
- Sulfur dioxide → acid rain, which damages buildings, plants and lakes.
- Step 1: Count the atoms on the left: sulfur = 1 (from ) + 2 (from 2S) = 3, hydrogen = 4, oxygen = 2. Step 2: To balance sulfur, 3 S are needed; to balance the 4 hydrogen and 2 oxygen, 2 are needed (4 H and 2 O). Step 3: So the balanced equation is .Method:Count atoms of each element on both sides and choose coefficients that balance them.Examiner tips
- Balance the element appearing in fewest places first, then check H and O.
- Step 1: Sulfur and oxygen are both non-metals. Step 2: Non-metal atoms bond by sharing pairs of electrons, which is covalent bonding. Step 3: Ionic bonding is between metals and non-metals, and metallic bonding is in metals, so sulfur dioxide has covalent bonding.Method:Use the types of elements present to decide the bonding.Examiner tips
- Non-metal + non-metal = covalent bonding (shared electrons).
- Step 1: There are 2 Al = 2 × 27 = 54, and 3 sulfate groups contain 3 S = 3 × 32 = 96 and 12 O = 12 × 16 = 192. Step 2: Add them: 54 + 96 + 192. Step 3: This gives a relative formula mass of 342.Method:Multiply each element atom count by its relative atomic mass and add the totals.Examiner tips
- contains 3 S and 12 O atoms in total.
- Step 1: Petroleum is separated by using the different boiling points of its hydrocarbons. Step 2: This separation of a liquid mixture by boiling point is called fractional distillation. Step 3: Cracking breaks molecules up, polymerisation joins them and electrolysis splits ionic compounds, so the separation process is fractional distillation.Method:Name the boiling-point separation used on crude oil.Examiner tips
- Fractional distillation separates petroleum using boiling point differences.
- Step 1: Fuel oil is a heavier fraction of petroleum used for large-scale heating. Step 2: It is used as a fuel for ships and in home heating systems. Step 3: Drinks are not made from fuel oil, jet engines use kerosene and roads are surfaced with bitumen, so the use is fuel for ships or home heating.Method:Recall the typical use of the fuel oil fraction.Examiner tips
- Fuel oil → fuel for ships and home heating.
- Step 1: Natural gas is mostly made up of the smallest alkane. Step 2: The main constituent of natural gas is methane, . Step 3: Ethane is only a minor component, ethanol is an alcohol and carbon dioxide is not a fuel, so the main constituent is methane.Method:Recall the main compound found in natural gas.Examiner tips
- Natural gas ≈ methane, the simplest alkane.
- Step 1: Breaking long chain hydrocarbons into shorter ones is called cracking. Step 2: Cracking needs a catalyst and a high temperature to break the strong carbon-carbon bonds. Step 3: The products are a smaller, more useful alkane together with an alkene (and sometimes hydrogen), so the correct option names cracking with catalyst, high temperature, alkane + alkene.Method:Identify the process, then state its conditions and products together.Examiner tips
- Cracking = heat + catalyst to break long chains into a smaller alkane + an alkene.
- Step 1: Cracking produces shorter hydrocarbons such as petrol and useful alkenes. Step 2: These shorter molecules are in greater demand and are more useful than the surplus long chain molecules. Step 3: So a reason for cracking is that the products are more useful and in greater demand.Method:Recall the economic reason for cracking long hydrocarbons.Examiner tips
- We crack because the smaller products are more useful and in greater demand.
- Step 1: Ethane is a saturated alkane with formula . Step 2: The two carbon atoms are joined by a single C-C bond, and each carbon forms three more bonds to hydrogen, giving six C-H bonds. Step 3: This uses all four bonds on each carbon, so the displayed formula shows a C-C single bond with three H on each carbon.Method:Give each carbon four single bonds: one to the other carbon and three to hydrogen.Examiner tips
- Each carbon forms 4 bonds; in ethane that is 1 C-C and 3 C-H.
- Step 1: Fermentation uses yeast, which provides the enzymes that convert glucose to ethanol. Step 2: It works best at a warm temperature of about 25-35 °C and in the absence of oxygen (anaerobic). Step 3: A metal catalyst, high temperatures, excess oxygen or freezing are not used, so the correct conditions are yeast and a warm 25-35 °C.Method:Recall the conditions under which yeast ferments glucose to ethanol.Examiner tips
- Fermentation: yeast + warm (25-35 °C) + anaerobic conditions.
- Step 1: Ethanol mixes with many substances and burns cleanly. Step 2: It is therefore widely used as a solvent (for example in perfumes) and as a fuel. Step 3: Ethanol is not a metal, a balloon gas or an acid, so a correct use is as a solvent or fuel.Method:Recall a common everyday use of ethanol.Examiner tips
- Ethanol uses: solvent and fuel.
- Step 1: The molecular formula is found by counting each type of atom in the displayed formula. Step 2: There are 6 carbon atoms, 10 hydrogen atoms and 3 oxygen atoms. Step 3: Writing these as a molecular formula gives .Method:Count every carbon, hydrogen and oxygen atom and write them as a molecular formula.Examiner tips
- Molecular formula = a simple count of each atom shown in the displayed formula.
- Step 1: An unsaturated molecule is one that contains a carbon-carbon double bond. Step 2: This C=C bond can open up to add other atoms, which is the test for an unsaturated compound. Step 3: Single bonds only would be saturated, and oxygen atoms or the H-to-C ratio do not decide saturation, so it is unsaturated because of the C=C double bond.Method:Link the term unsaturated to the presence of a C=C double bond.Examiner tips
- Unsaturated molecules have at least one C=C double bond.
- Step 1: The more vigorously a metal reacts with acid (the more bubbles of hydrogen), the more reactive it is. Step 2: D fizzes most, so D is most reactive, followed by A, then B. Step 3: C fizzes least, so it is least reactive, giving the order D, A, B, C.Method:Use the amount of bubbling to rank the metals from most to least reactive.Examiner tips
- Rank metals by the vigour of their reaction with acid.
- Step 1: Rate increases when particles collide more often or more energetically. Step 2: Increasing the temperature gives particles more energy, and using smaller pieces of metal increases the surface area, so both speed up the reaction (adding a catalyst would too). Step 3: Cooling, using one large lump, or diluting the acid all slow the reaction, so the correct pair is higher temperature and larger surface area.Method:Recall the factors that increase reaction rate, excluding concentration which is already given.Examiner tips
- Rate factors: temperature, concentration, surface area, catalyst.
- Step 1: Hydrogen is tested using a lighted splint. Step 2: The hydrogen burns rapidly with a characteristic squeaky pop. Step 3: A glowing splint relighting tests for oxygen, limewater tests for carbon dioxide and damp red litmus tests for ammonia, so hydrogen gives a squeaky pop with a lighted splint.Method:Match the gas to its test and observation: hydrogen gives a squeaky pop.Examiner tips
- The squeaky pop with a lighted splint is the hydrogen test.
- Step 1: Acids produce hydrogen ions when dissolved in water. Step 2: So the ion present in all aqueous acids is the hydrogen ion, . Step 3: Hydroxide ions are found in alkalis, and chloride and oxide ions are not what make a solution acidic, so the ion is .Method:Recall the ion that defines an acidic solution.Examiner tips
- Acid = source of ; alkali = source of .
- Step 1: An alloy is made by mixing a metal with other elements, usually other metals. Step 2: So an alloy is a mixture of a metal with one or more other elements. Step 3: It is not a compound, not a pure metal and not a coating, so the correct meaning is a mixture of a metal with other elements.Method:Recall the definition of an alloy as a mixture.Examiner tips
- Alloy = mixture of a metal with one or more other elements.
- Step 1: Cutlery must stay strong and not corrode when washed and used with food. Step 2: Stainless steel is hard and resists rusting, so it stays clean and keeps its edge. Step 3: Rusting, a low melting point or dissolving would all make it unsuitable, so the useful property is being hard and rust-resistant.Method:Match a property of stainless steel to the needs of cutlery.Examiner tips
- Stainless steel: hard + rust-resistant = good for cutlery.
- Step 1: An acid reacting with a metal carbonate gives a salt, carbon dioxide and water. Step 2: The salt is named from the metal (magnesium) and the acid (nitric acid → nitrate), giving magnesium nitrate. Step 3: So the products are magnesium nitrate, carbon dioxide and water.Method:Apply the acid-plus-carbonate pattern and name the salt from the acid used.Examiner tips
- Acid + carbonate always makes salt + CO₂ + water.
- Step 1: Excess copper(II) oxide is filtered off so only the copper(II) chloride solution remains. Step 2: The solution is heated and evaporated to the point of crystallisation (until crystals just start to form). Step 3: The crystals are then removed and dried between sheets of filter paper, giving pure, dry copper(II) chloride.Method:Remove the excess solid, crystallise by evaporation, then dry the crystals.Examiner tips
- Salt prep with excess base: filter → evaporate to crystallisation → dry.
- Step 1: The anode is the positive electrode in electrolysis. Step 2: The right-hand electrode is connected to the positive terminal, so it is the anode. Step 3: The left-hand electrode (negative terminal) is the cathode, and heat position does not decide it, so the anode is the right-hand (positive) electrode.Method:Identify the positive electrode as the anode.Examiner tips
- Anode is positive; cathode is negative ("an ox, red cat").
- Step 1: An inert electrode does not react during electrolysis. Step 2: Besides platinum, graphite (carbon) is the common inert electrode material because it conducts electricity and is unreactive. Step 3: Copper and iron are reactive metals used as non-inert electrodes, and sodium is far too reactive, so the answer is graphite/carbon.Method:Recall the common inert electrode materials.Examiner tips
- Inert electrodes: platinum and graphite (carbon).
- Step 1: In molten lithium iodide the ions are and . Step 2: Positive iodide ions are attracted to the negative electrode? No: negative iodide ions move to the positive electrode (anode) and form iodine, while positive lithium ions move to the negative electrode (cathode) and form lithium. Step 3: So iodine forms at the positive electrode and lithium at the negative electrode.Method:Send positive metal ions to the cathode and negative non-metal ions to the anode.Examiner tips
- Molten binary salt: metal at cathode (−), non-metal at anode (+).
- Step 1: Simple molecular compounds have low melting points (weak forces between molecules) and do not conduct electricity because they have no free ions or electrons. Step 2: Compound B (−157 °C, non-conducting) and compound E (−83 °C, non-conducting) both fit this description. Step 3: Compounds A, C and D have high melting points or conduct when molten, so they are not simple molecules; the two simple molecular compounds are therefore B and E.Method:Select the compounds with both a low melting point and no conductivity when molten.Examiner tips
- Pick the compounds that are BOTH low-melting AND non-conducting when molten.
- Step 1: Work out the size of each temperature change: experiment 1 = 6 °C, experiment 2 = 8 °C, experiment 3 = 4 °C, experiment 4 = 7 °C. Step 2: The largest of these is 8 °C. Step 3: That is experiment 2, so it shows the greatest temperature change.Method:Calculate each temperature change and choose the largest.Examiner tips
- Greatest temperature change = largest difference (ignore the direction).
- Step 1: contains 2 chlorine atoms, so 2 HCl are needed to supply them. Step 2: The 2 HCl provide 2 hydrogen atoms, which form one molecule of hydrogen gas, . Step 3: So the balanced equation is .Method:Balance the chlorine atoms first, then identify the hydrogen gas product.Examiner tips
- Balance chlorine first (2 Cl needs 2 HCl), then the hydrogen forms .
- Step 1: The vertical axis of a reaction pathway diagram is energy. Step 2: The reactants are drawn on the left and the products on the right. Step 3: Because the reaction is exothermic, the products are at a lower energy than the reactants, so the products line is lower on the right.Method:Label energy on the y-axis and place reactants left, products lower right.Examiner tips
- Exothermic: products lower than reactants on an energy (y) vs progress (x) diagram.
- Step 1: Change G goes from liquid to gas, which is evaporation (boiling). Step 2: Change H goes from liquid to solid, which is freezing. Step 3: Condensation is gas to liquid and melting is solid to liquid, so G is evaporation and H is freezing.Method:Identify the start and end states of each change and name it.Examiner tips
- Name the change by its start and end state: liquid→gas evaporation, liquid→solid freezing.
- Step 1: Activated carbon is added to absorb substances that cause unpleasant tastes and odours. Step 2: Chlorination adds chlorine to kill harmful microbes (bacteria) so the water is safe to drink. Step 3: So carbon removes tastes and odours while chlorination kills microbes.Method:Match each treatment stage to the problem it solves.Examiner tips
- Water treatment: carbon for taste/odour, chlorine to kill microbes.
- Step 1: Pure water has a fixed boiling point of exactly 100 °C at normal pressure. Step 2: Heat the sample and measure the temperature at which it boils. Step 3: If it boils at exactly 100 °C it is pure; if it boils above 100 °C it contains dissolved impurities, so measuring the boiling point tests the purity.Method:Measure the boiling point and compare it with the value for pure water.Examiner tips
- Purity test: measure boiling point; pure water boils at exactly 100 °C.
- Step 1: Tap water contains dissolved substances such as salts and chlorine. Step 2: Distilling removes these, so distilled water contains far fewer impurities. Step 3: Fewer impurities means they cannot interfere with reactions or results, which is why distilled water is used rather than tap water.Method:Explain the preference in terms of the impurity content of the water.Examiner tips
- Distilled water = very few impurities, so it does not interfere with experiments.
- Step 1: Carbon monoxide is a toxic gas that combines with the blood and reduces oxygen transport, so it is poisonous. Step 2: Methane is a greenhouse gas that traps heat and causes global warming (climate change). Step 3: So carbon monoxide is toxic and methane causes global warming.Method:Recall the harmful effect linked to each named pollutant.Examiner tips
- Carbon monoxide = poisonous; methane = greenhouse gas (global warming).
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